Cleavage (crystal)


Cleavage (crystal)

Cleavage (crystal)

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Cleavage (crystal)

Green fluorite with prominent cleavage.

Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness create smooth repeating surfaces.[1]

Contents

[] Types of cleavage

Cleavage forms parallel to crystallographic planes:[1]

Biotite with basal cleavage.
  • Basal or pinacoidal cleavage occurs parallel to the base of a crystal. This orientation is given by the {001} plane in the crystal lattice (see Miller indices), and is the same as the {0001} plane in Bravais-Miller indices, which are often used for rhombohedral and hexagonal crystals. Basal cleavage is exhibited by the mica group and by graphite.
  • Cubic cleavage occurs on the {001} planes parallel to the faces of a cube. This is the source of the cubic shape seen in crystals of ground table salt, the mineral halite. The mineral galena also typically exhibits perfect cubic cleavaage.
  • Octahedral cleavage occurs on the {111} crystal planes forming octahedra shapes. Diamond and fluorite exhibit perfect octahedral cleavage. Octahedral cleavage is seen in common semiconductors.
  • Dodecahedral cleavage occurs on the {011} crystal planes forming dodecahedra. Wulfenite and gypsum exhibit dodecahedral cleavage.

[] Parting

Crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only occur due to stress. Examples include magnetite which shows octahedral parting, the rhombohedral parting of corundum and basal parting in pyroxenes.[1]

[] Uses

Cleavage is a traditional physical property used in mineral identification both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the prismatic cleavage planes for the pyroxenes (88-92°) and the amphiboles (56-124°) are diagnostic.[1]

Crystal cleavage is of technical importance in the electronics industry and in the cutting of gemstones.

Precious stones are generally cleaved by impact as in diamond cutting.

Synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Simply pressing a silicon wafer against a soft surface and scratching its edge with a diamond scribe is usually enough to cause cleavage; however, when dicing a wafer to form chips, a procedure of scoring and breaking is often followed for greater control. Elemental semiconductors (Si, Ge, and diamond) are diamond cubic, a space group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved. Most other commercial semiconductors (GaAs, InSb, etc.) can be made in the related zinc blende structure, with similar cleavage planes.

[] See also

[] References

  1. ^ a b c d * Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, ISBN 0-471-80580-7


Green fluorite with prominent cleavage.

Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness create smooth repeating surfaces.[1]

Contents

[] Types of cleavage

Cleavage forms parallel to crystallographic planes:[1]

Biotite with basal cleavage.
  • Basal or pinacoidal cleavage occurs parallel to the base of a crystal. This orientation is given by the {001} plane in the crystal lattice (see Miller indices), and is the same as the {0001} plane in Bravais-Miller indices, which are often used for rhombohedral and hexagonal crystals. Basal cleavage is exhibited by the mica group and by graphite.
  • Cubic cleavage occurs on the {001} planes parallel to the faces of a cube. This is the source of the cubic shape seen in crystals of ground table salt, the mineral halite. The mineral galena also typically exhibits perfect cubic cleavaage.
  • Octahedral cleavage occurs on the {111} crystal planes forming octahedra shapes. Diamond and fluorite exhibit perfect octahedral cleavage. Octahedral cleavage is seen in common semiconductors.
  • Dodecahedral cleavage occurs on the {011} crystal planes forming dodecahedra. Wulfenite and gypsum exhibit dodecahedral cleavage.

[] Parting

Crystal parting occurs when minerals break along planes of structural weakness due to external stress or along twin composition planes. Parting breaks are very similar in appearance to cleavage, but only occur due to stress. Examples include magnetite which shows octahedral parting, the rhombohedral parting of corundum and basal parting in pyroxenes.[1]

[] Uses

Cleavage is a traditional physical property used in mineral identification both in hand specimen and microscopic examination of rock and mineral studies. As an example, the angles between the prismatic cleavage planes for the pyroxenes (88-92°) and the amphiboles (56-124°) are diagnostic.[1]

Crystal cleavage is of technical importance in the electronics industry and in the cutting of gemstones.

Precious stones are generally cleaved by impact as in diamond cutting.

Synthetic single crystals of semiconductor materials are generally sold as thin wafers which are much easier to cleave. Simply pressing a silicon wafer against a soft surface and scratching its edge with a diamond scribe is usually enough to cause cleavage; however, when dicing a wafer to form chips, a procedure of scoring and breaking is often followed for greater control. Elemental semiconductors (Si, Ge, and diamond) are diamond cubic, a space group for which octahedral cleavage is observed. This means that some orientations of wafer allow near-perfect rectangles to be cleaved. Most other commercial semiconductors (GaAs, InSb, etc.) can be made in the related zinc blende structure, with similar cleavage planes.

[] See also

[] References

  1. ^ a b c d * Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, ISBN 0-471-80580-7